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Beilstein J. Org. Chem. 2011, 7, 847–859, doi:10.3762/bjoc.7.97
Graphical Abstract
Scheme 1: Mechanistic scenarios for alkyne activation.
Scheme 2: Synthesis of 3(2H)-furanones.
Scheme 3: Synthesis of furans.
Scheme 4: Formation of dihydrooxazoles.
Scheme 5: Variation on indole formation.
Scheme 6: Formation of naphthalenes.
Scheme 7: Formation of indenes.
Scheme 8: Iodocyclization of 3-silyloxy-1,5-enynes.
Scheme 9: 5-Endo cyclizations with concomitant nucleophilic trapping.
Scheme 10: Reactivity of 3-BocO-1,5-enynes.
Scheme 11: Intramolecular nucleophilic trapping.
Scheme 12: Approach to azaanthraquinones.
Scheme 13: Carbocyclizations with enol derivatives.
Scheme 14: Gold-catalyzed cyclization modes for 1,5-enynes.
Scheme 15: Iodine-induced cyclization of 1,5-enynes.
Scheme 16: Diverse reactivity of 1,6-enynes.
Scheme 17: Iodocyclization of 1,6-enynes.
Scheme 18: Cyclopropanation of alkenes with 1,6-enynes.
Scheme 19: Cyclopropanation of alkenes with 1,6-enynes.